Removal of estrogen hormones (17-beta-estradiol and estrone) from aqueous solutions using rice husk silica

The aim of this study was to investigate the removal of estrogen hormones (17β-estradiol and estrone) from aqueous solutions using rice husk extracted silica. Rice husk was collected from rice factories in Mazandaran province (Iran) and the adsorbent was prepared in a furnace at 800 °C for 4 h, afte...

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Permalink: http://skupnikatalog.nsk.hr/Record/nsk.NSK01001068883/Details
Matična publikacija: Chemical & biochemical engineering quarterly (Online)
33 (2019), 2 ; str. 281-293
Glavni autori: Zarghi, Mohammad Hasan (Author), Roudbari, Aliakbar, Jorfi, Sahand, Jaafarzadeh, Neamat
Vrsta građe: e-članak
Jezik: eng
Predmet:
Online pristup: https://doi.org/10.15255/CABEQ.2018.1542
Chemical & biochemical engineering quarterly (Online)
Hrčak
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100 1 |a Zarghi, Mohammad Hasan  |4 aut  |9 HR-ZaNSK 
245 1 0 |a Removal of estrogen hormones (17-beta-estradiol and estrone) from aqueous solutions using rice husk silica  |h [Elektronička građa] /  |c Mohammad Hasan Zarghi, Aliakbar Roudbari, Sahand Jorfi, Neamat Jaafarzadeh. 
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504 |a Bibliografija: 59 jed. 
504 |a Summary. 
520 |a The aim of this study was to investigate the removal of estrogen hormones (17β-estradiol and estrone) from aqueous solutions using rice husk extracted silica. Rice husk was collected from rice factories in Mazandaran province (Iran) and the adsorbent was prepared in a furnace at 800 °C for 4 h, after acid leaching with hydrochloric and sulfuric acid mixture. Optimal operating parameters for estrogen removal were determined, including initial pH values (4–9), adsorbent dosages (0.5, 1, 1.5, and 2 g L–1), contact times (30, 60, 90, and 120 min), and initial concentrations of 17β-estradiol and estrone (10, 40, 70 and 100 ng L–1); one-factor-at-a-time method was used. The method of electrochemiluminescence was used to measure the concentration of hormones. Kinetic adsorption models and adsorption isotherms were also studied. The maximum removal efficiency (%) of 17β-estradiol (E2) and estrone (E1) hormones of 95.5 and 93.1 %, respectively, was obtained at optimal conditions of pH 4, 1.5 g L–1 of adsorbent dosage, 60 min of contact time and 10 ng L–1 initial concentrations of E2 and E1. Pseudo first-order kinetic model and Langmuir adsorption isotherm had the best fit with experimental data for both estrogen hormones, following nonlinear regression procedure. Rice husk silica could be considered as effective and accessible adsorbent for removal of estrogenic hormones. 
653 0 |a Steroidni hormoni  |a Estrogeni  |a Otpadne vode  |a Površinske vode  |a Podzemne vode  |a Uklanjanje  |a Adsorpcija  |a Rižina ljuska  |a Silicij 
700 1 |a Roudbari, Aliakbar  |4 aut  |9 HR-ZaNSK 
700 1 |a Jorfi, Sahand  |4 aut 
700 1 |a Jaafarzadeh, Neamat  |4 aut  |9 HR-ZaNSK 
773 0 |t Chemical & biochemical engineering quarterly (Online)  |x 1846-5153  |g 33 (2019), 2 ; str. 281-293  |w nsk.(HR-ZaNSK)000622963 
981 |b Be2019  |b B04/19 
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856 4 0 |u https://doi.org/10.15255/CABEQ.2018.1542 
856 4 0 |u http://silverstripe.fkit.hr/cabeq/past-issues/article/1542  |y Chemical & biochemical engineering quarterly (Online) 
856 4 0 |u https://hrcak.srce.hr/223899  |y Hrčak 
856 4 1 |y Digitalna.nsk.hr